Engine exhaust emission purification apparatus

ABSTRACT

An engine exhaust emission purification apparatus for reducing and purifying NOx in the exhaust emission by using a liquid reducing agent having a temperature maintenance device for maintaining a temperature of at least a part of a liquid reducing agent supply system configured by an injection nozzle and piping of the injection nozzle at a temperature lower than a boiling point of a solvent of the liquid reducing agent or equal to or higher than a melting point of dissolved matter in which the liquid reducing agent existing in the liquid reducing agent supply system conducts heat exchange with the liquid reducing agent supply system thereby being maintained at a temperature lower than the boiling point of the solvent or equal to or higher than the melting point of the dissolved matter and resultantly, occurrence of precipitation of the dissolved matter due to evaporation of only the solvent in the liquid reducing agent supply system does not occur, and even if precipitation of the dissolved matter occurs, the dissolved matter per se is melt away to prevent an injection hole of the injection nozzle from being clogged.

This application is a divisional application of U.S. application Ser.No. 10/572,573, which was the National Stage of InternationalApplication No. PCT/JP2004/013608, filed Sep. 17, 2004.

BACKGROUND OF THE INVENTION

1. Field of the Invention

The present invention relates to an engine exhaust emission purificationapparatus for reducing and purifying nitrogen oxides (NOx) in an exhaustemission by using a liquid reducing agent (hereafter referred to as“exhaust emission purification apparatus”) and particularly to atechnology for rarely causing clogging of an injection hole of aninjection nozzle for the liquid reducing agent.

2. Description of the Related Art

As an exhaust emission purification system for purifying NOx included inan engine exhaust emission, there has been proposed an exhaust emissionpurification apparatus as disclosed in Japanese Patent ApplicationLaid-open No. 2000-27627.

In this exhaust emission purification apparatus, a reduction catalyticconverter is disposed in an exhaust system of the engine, a reducingagent is supplied by injection to an exhaust emission at a positionupstream of the reduction catalytic converter, and NOx in the exhaustemission is subjected to reaction with the reduction agent in thereduction catalytic converter for purifying the exhaust emission byconverting the NOx into harmless components. The reducing agent isstored in a storage tank in a liquid state at room temperature and isinjected and supplied from an injection nozzle in a required amountcorresponding to an operating state of the engine. At this stage, as thereducing agent, a liquid reducing agent such as a urea aqueous solution,an ammonia aqueous solution, and diesel oil having hydrocarbon as maincomponents is used.

However, with the conventional exhaust emission purification apparatus,the injection hole of the injection nozzle might be clogged during thesupply of the liquid reducing agent by injection and the injection forsupplying the liquid reducing agent will become impossible in somecases. As a result, the reduction reaction of NOx in the reductioncatalytic converter would not proceed to result in emission of the NOxbefore it is purified and therefore, it might become impossible toobtain a required performance for the exhaust emission purification. Itis assumed that this problem is caused by such a phenomenon that only asolvent evaporates and the dissolved matter of the liquid reducing agentis precipitated in the injection nozzle when a temperature of theinjection nozzle increases under an influence of exhaust heat and atemperature of the liquid reducing agent increases to or over a boilingpoint of the solvent.

In the injection nozzle, when the temperature of the liquid reducingagent increases to or over the boiling point of the solvent and thedissolved matter is precipitated and when the temperature furtherincreases over a melting point of the dissolved matter, the dissolvedmatter melts and therefore the clogging of the injection hole isexpected to be cancelled.

On the other hand, at a portion less susceptible to the heat of exhaustemission, e.g., piping for supplying the liquid reducing agent to theinjection nozzle, a temperature increases to or over the boiling pointof the solvent but may not increase to or over the melting point of thedissolved matter. In this case, the dissolved matter remainsprecipitated in the injection nozzle and the piping for the nozzle, andtherefore it becomes impossible to make an injection supply of theliquid reducing agent from the injection nozzle. As a result, exhaustemission purification by the reduction catalytic converter may becomeinsufficient to resultantly cause emission of a large amount of NOx.Such a problem becomes prominent especially when the injection supply ofthe liquid reducing agent stop under a condition where the temperaturesof the injection nozzle and the piping for the nozzle equal to or higherthan the boiling point of the solvent or when an amount of liquidreducing agent supplied by injection is small.

SUMMARY OF THE INVENTION

Therefore, taking into account the above problems of the conventionalapparatus, it is an object of the present invention to provide anexhaust emission purification apparatus in which clogging of aninjection hole of an injection nozzle may be prevented by maintaining atemperature of at least a part of a liquid reducing agent supply systemprovided with an injection nozzle and piping for the nozzle at atemperature lower than a boiling point of a solvent or equal to orhigher than a melting point of dissolved matter.

Therefore, in accordance with the present invention, there is providedan engine exhaust emission purification apparatus, which comprises: areduction catalytic converter disposed in an engine exhaust system toreduce and purify nitrogen oxides by using a liquid reducing agent; aninjection nozzle for supplying the liquid reducing agent by injection tothe emission at a position upstream the reduction catalytic converter;and a temperature maintenance device for maintaining a temperature of atleast a part of a liquid reducing agent supply system provided with theinjection nozzle and the piping of the nozzle at a temperature lowerthan a boiling point of a solvent of the liquid reducing agent or equalto or higher than a melting point of dissolved matter.

The temperature maintenance device may be formed of a heat insulatingmember disposed between the exhaust system and a flange for mounting theinjection nozzle to the exhaust system, may be formed of radiating finsprovided to be juxtaposed to the flange for attaching the injectionnozzle to the exhaust system, or may be formed by routing a conduit forengine coolant, i.e., an engine coolant, to the flange for attaching theinjection nozzle to the exhaust system so as to cause heat exchangebetween the flange and the engine coolant in the conduit.

Further, the temperature maintenance device may be formed by leading aconduit for engine coolant to at least a part of the liquid reducingagent supply system so as to cause heat exchange between the liquidreducing agent supply system and the engine coolant. At this time, anozzle temperature detecting device for detecting a nozzle temperatureof the injection nozzle and a circulation control device for circulatingor intercepting the engine coolant in the conduit based on the nozzletemperature detected by the nozzle temperature detecting device arepreferably provided. The engine coolant is circulated by flow when thenozzle temperature is equal to or higher than the boiling point of thesolvent of the liquid reducing agent or lower than the melting point ofthe dissolved matter. Furthermore, it is preferable that a coolanttemperature detecting device for detecting a temperature of the enginecoolant is provided and that the circulation of the engine coolant byflow is prohibited when the coolant temperature detected by the coolanttemperature detecting device is equal to or higher than the boilingpoint of the solvent of the liquid reducing agent.

On the other hand, the temperature maintenance device may include aheating device such as a heater for heating at least a part of theliquid reducing agent supply system and a heating control device forcontrolling the heating device. A heat insulating member may preferablybe disposed around at least a part of the liquid reducing agent supplysystem and the heating device. At this time, it is preferable that anozzle temperature detecting device for detecting a nozzle temperatureof the injection nozzle is provided and that actuation of the heatingdevice is controlled based on the nozzle temperature detected by thenozzle temperature detecting device. Moreover, at least a part of theliquid reducing agent supply system may preferably be heated to atemperature equal to or higher than the melting point of the dissolvedmatter of the liquid reducing agent by using the heating device when theinjection supply of the liquid reducing agent is stopped.

With the exhaust emission purification apparatus according to theinvention, at least a part of the liquid reducing agent supply systemprovided with the injection nozzle and the associated piping for theinjection nozzle is maintained by the temperature maintenance device ata temperature either lower than the boiling point of the solvent of theliquid reducing agent or equal to or higher than the melting point ofthe dissolved matter. Therefore, the liquid reducing agent existing inthe liquid reducing agent supply system implements heat exchange withthe liquid reducing agent supply system to thereby be maintained at atemperature lower than the boiling point of the solvent or at atemperature equal to or higher than the melting point of the dissolvedmatter. Therefore, a phenomenon in which only the solvent evaporates inthe liquid reducing agent supply system and the dissolved matter isprecipitated does not occur. If the dissolved matter is precipitated,the dissolved matter melts away. As a result, clogging of an injectionhole of the injection nozzle may be prevented. Because injection/supplyfailure of the liquid reducing agent is avoided, a required amount ofliquid reducing agent according to an operating state of the engine canbe injection-supplied to obtain necessary exhaust emission purificationperformance.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 shows a basic structure of an exhaust emission purificationapparatus according to the present invention;

FIG. 2 is an explanatory view of a first embodiment of a temperaturemaintenance device;

FIG. 3 is an explanatory view of a second embodiment of the temperaturemaintenance device;

FIG. 4 is an explanatory view of a third embodiment of the temperaturemaintenance device;

FIG. 5 is an enlarged view of an essential portion of the above;

FIG. 6 is a flow chart showing contents of control of an opening/closingvalve;

FIG. 7 is an explanatory view of a fourth embodiment of the temperaturemaintenance device;

FIG. 8 is an enlarged view of an essential portion of the above;

FIG. 9 is an explanatory view of a fifth embodiment of the temperaturemaintenance device;

FIG. 10 is an explanatory view of a sixth embodiment of the temperaturemaintenance device;

FIG. 11 is an enlarged view of an essential portion of the above;

FIG. 12 is a flow chart showing contents of control of a heater; and

FIG. 13 is an explanatory view of a seventh embodiment of thetemperature maintenance device.

DESCRIPTION OF THE PREFERRED EMBODIMENT

The present invention will be described below in detail with referenceto the accompanying drawings.

FIG. 1 shows a basic structure of an exhaust emission purificationapparatus according to the invention. Exhaust emission from an engine 10is emitted into the air from an exhaust pipe 16 in which a NOx reductioncatalytic converter 14 is disposed through an exhaust manifold 12.Specifically, in the exhaust pipe 16, three catalytic converters, i.e.,a nitrogen monoxide (NO) oxidation catalytic converter, a NOx reductioncatalytic converter, and an ammonia slip oxidation catalytic converterare disposed in order from an upstream side of the flow of the exhaustemission, and a temperature sensor and so on are disposed in front andat the rear of the catalytic converters to thereby form an exhaustsystem. However, details are not illustrated for the simplicity sake.

In the exhaust pipe 16 located on the exhaust emission upstream side ofthe NOx reduction catalytic converter 14, an injection nozzle 20 isattached to the pipe 16, via a flange 18 fastened to a peripheral wallof the pipe 16. The injection nozzle 20 implements injection-supply of aliquid reducing agent to the exhaust emission flowing upstream side ofthe NOx reduction catalytic converter 14 and a tip end portion of thenozzle 20 is formed with an injection hole for spraying and injectingthe liquid reducing agent. Piping 22 in fluid communication with theinjection nozzle 20 is connected to the flange 18, and a reducing agentsupply device 24 for supplying the liquid reducing agent is connected tothe piping 22. To the exhaust emission upstream side of the NOxreduction catalytic converter 14, a required amount of liquid reducingagent according to an operating state of the engine isinjection-supplied together with air from the reducing agent supplydevice 24 through the piping 22 and the injection nozzle 20. Although aurea aqueous solution is used as the liquid reducing agent in thepresent embodiment, an ammonia aqueous solution may be used (hereafterthe same shall apply).

The urea aqueous solution injected and supplied from the injectionnozzle 20 is hydrolyzed due to heat of the exhaust emission and watervapor in the exhaust emission and converted into ammonia. It is knownthat ammonia reacts with NOx in the exhaust emission within the NOxreduction catalytic converter 14 and converts and purifies the emissionto water and harmless gas. The urea aqueous solution is an aqueoussolution of solid or powder urea, introduced by suction from an inletport 28 formed in a vicinity of a bottom portion of a storage tank 26and supplied to the reducing agent supply device 24 via supply piping30.

Here, the invention is provided with a temperature maintenance devicefor maintaining a temperature of at least a part of a urea aqueoussolution supply system provided with the injection nozzle 20 and piping22 for the nozzle at a temperature lower than a boiling point (100° C.)of a solvent (water) of the urea aqueous solution or equal to or higherthan a melting point (132° C.) of dissolved matter (urea). Variousembodiments of the temperature maintenance device will be describedhereinbelow.

FIG. 2 shows a first embodiment of the temperature maintenance device.

The temperature maintenance device is formed of a heat insulatingmember, e.g., a gasket 32 made of material with low thermal conductivitydisposed between the exhaust pipe 16 and the flange 18. With thisstructure, heat of the exhaust emission from the engine 10 is insulatedby the gasket 32 and therefore becomes less likely to be transferred tothe flange 18. Then, increase in a temperature of the flange 18 issuppressed and the temperature is maintained at a temperature lower thanthe boiling point of water. As a result, the temperatures of theinjection nozzle 20 and the piping 22 connected to the flange 18 becomelower than the boiling point of water. Therefore, a phenomenon in whichonly moisture evaporates from the urea aqueous solution and urea isprecipitated becomes less likely to occur to thereby avoidinjection/supply failure of the urea aqueous solution caused by cloggingof the injection hole of the injection nozzle 20. Therefore, a requiredamount of urea aqueous solution according to the operating state of theengine can be injection-supplied to obtain necessary exhaust emissionpurification performance.

FIG. 3 shows a second embodiment of the temperature maintenance device.

The temperature maintenance device is formed of a plurality of radiatingfins 34 provided to be juxtaposed to an outer surface of the flange 18.With this structure, even when the exhaust heat of the engine 10 istransferred to the flange 18, the heat is radiated from the radiatingfins 34 into the air to thereby suppress an increase in the temperatureof the flange 18 and maintain the temperature at a temperature valuelower than the boiling point of water. As a result, the temperatures ofthe injection nozzle 20 and the piping 22 connected to the flange 18become lower than the boiling point of water to thereby exert similaradvantageous effects to those exhibited by the preceding firstembodiment.

FIGS. 4 and 5 show a third embodiment of the temperature maintenancedevice.

In the temperature maintenance device, a conduit 36 of engine coolant,i.e., engine coolant is led into the flange 18 so that the flange 18 andthe engine coolant carries out heat exchange with each other. Theconduit 36 is interposed with an electromagnetic opening/closing valve38 for opening/closing a channel of the conduit 36 so as to circulate orintercept the engine coolant. A control unit 40 which has a built-incomputer controls opening and closing of the opening/closing valve 38based on detection signals from a coolant temperature sensor 42 (coolanttemperature detecting device) for detecting a temperature TW of theengine coolant and a nozzle temperature sensor 44 (nozzle temperaturedetecting device) for detecting a nozzle temperature TN of the injectionnozzle 20. Cooperation of the opening/closing valve 38 with the controlunit 40, a circulation control device is formed.

FIG. 6 shows contents of processing performed repeatedly everypredetermined time in the control unit 40.

At step 1 (abbreviated as “S1” in the drawings and hereafter the sameshall apply), the coolant temperature TW is read in from the coolanttemperature sensor 42.

At step 2, whether the coolant temperature TW is lower than the boilingpoint Ta of the water or not is determined. If the coolant temperatureTW is lower than the boiling point Ta, the processing goes to step 3(Yes). If the coolant temperature TW is equal to or higher than theboiling point Ta, the processing goes to step 6 (No).

At step 3, the nozzle temperature TN is read in from the nozzletemperature sensor 44.

At step 4, it is determined whether or not the nozzle temperature TN isequal to or higher than the boiling point Ta. If the nozzle temperatureTN is equal to or higher than the boiling point Ta, the processing goesto step 5 (Yes) to open the opening/closing valve 38. On the other hand,if the nozzle temperature TN is lower than the boiling point Ta, theprocessing goes to step 6 (No) to close the opening/closing valve 38.

With this structure, when the nozzle temperature TN, i.e., thetemperature of the supply system of the urea aqueous solution is equalto or higher than the boiling point Ta of water, the opening/closingvalve 38 is opened and therefore the engine coolant maintained at about80° C. is led to the flange 18. Therefore, because the flange 18conducts heat exchange with the engine coolant, the temperature of theflange 18 is maintained at a temperature lower than the boiling point ofwater, specifically, about 80° C., even though the heat of the exhaustemission is transferred to the flange 18. At this time, if the coolanttemperature TW is equal to or higher than the boiling point Ta, theopening/closing valve 38 is closed irrespective of the nozzletemperature TN. Therefore, the high-temperature engine coolant is notled to the flange 18 to thereby prevent moisture from evaporating fromthe urea aqueous solution existing inside the injection nozzle 20 andthe piping 22. As a result, the temperatures of the injection nozzle 20and the piping 22 connected to the flange 18 become lower than theboiling point of water to thereby indicate similar advantageous effectsto the preceding embodiments.

It is possible to exhibit similar advantageous effects by determiningwhether or not the nozzle temperature TN is lower than a melting pointTb of urea instead of determining whether or not the nozzle temperatureTN is equal to or higher than the boiling point Ta of water. At thistime, if the nozzle temperature TN is equal to or higher than themelting point Th, the opening/closing valve 38 is closed and therefore,the engine coolant is not led to the flange 18 to thereby maintain thetemperature of the flange 18 at a temperature value equal to or higherthan the melting point Tb. Therefore, even if urea is precipitated inthe injection nozzle 20 and the piping 22, urea melts to thereby avoidinjection/supply failure of the urea aqueous solution caused by cloggingof the injection hole of the injection nozzle 20 (hereafter the sameshall apply).

FIGS. 7 and 8 show a fourth embodiment of the temperature maintenancedevice.

The temperature maintenance device is formed by spirally winding aconduit 46 of the engine coolant about at least a part of the supplysystem of the urea aqueous solution, e.g., a part of the piping 22connected to the flange 18. Here, circulation control of the enginecoolant is similar to that in the third embodiment.

With this structure, when the nozzle temperature TN, i.e., thetemperature of the supply system of the urea aqueous solution is equalto or higher than the boiling point Ta of water, the opening/closingvalve 38 is opened and therefore the engine coolant maintained at about80° C. is led to a periphery of the piping 22. Therefore, since thepiping 22 conducts heat exchange with the engine coolant, thetemperature of the piping 22 is maintained at a temperature value lowerthan the boiling point of water, specifically, about 80° C. As a result,the temperatures of the piping 22 and the injection nozzle 20 incommunication with and in connection to the piping 22 become lower thanthe boiling point of water so as to exhibit similar advantageous effectsto the preceding embodiments.

FIG. 9 shows a fifth embodiment of the temperature maintenance device.

The temperature maintenance device of this fifth embodiment isconfigured by arranging a conduit 48 for the flow of the engine coolantto be spirally wound around at least a part of the supply system of theurea aqueous solution, i.e., an area from the piping 22 to the injectionnozzle 20. Here, circulation control of the engine coolant is performedsimilarly to that performed in the third embodiment.

With this structure, when the nozzle temperature TN, i.e., thetemperature of the supply system of the urea aqueous solution is equalto or higher than the boiling point Ta of water, the opening/closingvalve 38 is opened and therefore, the engine coolant maintained at about80° C. is led to peripheries of the piping 22 and the injection nozzle20. Therefore, since the piping 22 and the injection nozzle 20 conductheat exchange with the engine coolant, the temperatures of the piping 22and the injection nozzle 20 are maintained at a temperature lower thanthe boiling point of water, specifically, about 80° C. As a result, thetemperatures of the piping 22 and the injection nozzle 20 become lowerthan the boiling point of water to thereby exhibit similar advantageouseffects to the preceding embodiments.

In the third to fifth embodiments, it is also possible to constantlycirculate the engine coolant through the conduit 36, 46, or 48 withoutperforming the control for circulating or intercepting the enginecoolant by using the opening/closing valve 38. In this way, the supplysystem of the urea aqueous solution or the flange 18 conducts heatexchange with the engine coolant and therefore, the temperature of thesupply system or the flange 18 is maintained at the temperature lowerthan the boiling point of water to thereby exhibit similar advantageouseffects to the respective preceding embodiments.

In a cold season of a temperature lower than a freezing temperature atwhich the urea aqueous solution freezes, the supply system of the ureaaqueous solution is heated by the engine coolant to thereby preventfreezing of the urea aqueous solution.

FIGS. 10 and 11 show a sixth embodiment of the temperature maintenancedevice.

The temperature maintenance device includes a heater 50 (heating device)wound about at least a part of the supply system of the urea aqueoussolution, e.g., a part of the piping 22 and a control unit 52 forcontrolling the heater 50. A heat insulating member 54 is disposedaround at least the part of the piping 22 and the heater 50. The heatinsulating member 54 is arranged to prevent heat radiation from theheater 50 toward outside, and is made of heat insulating material. Thecontrol unit 52 which has a built-in computer performs controlling ofactuation of the heater 50, based on a detection signal from a nozzletemperature sensor 56 (nozzle temperature detecting device) fordetecting the nozzle temperature TN of the injection nozzle 20.

FIG. 12 shows contents of processing performed repeatedly everypredetermined time in the control unit 52.

At step 11, the nozzle temperature TN is read in from the nozzletemperature sensor 56.

At step 12, it is determined whether or not the nozzle temperature TN isequal to or higher than the boiling point Ta of water and lower than themelting point Th of urea or not. If the nozzle temperature TN is equalto or higher than the boiling point Ta and lower than the melting pointTb, the processing goes to step 13 (Yes) to actuate the heater 50 so asto increase the temperature of the supply system of the urea aqueoussolution to or over the melting point Tb. If the nozzle temperature TNis lower than the boiling point Ta or equal to or higher than themelting point Tb, the processing goes to step 14 (No) to stop the heater50 so as to suppress unnecessary energy consumption, for example.

With this structure, if the nozzle temperature TN, i.e., the temperatureof the supply system of the urea aqueous solution is equal to or higherthan the boiling point Ta of water and lower than the melting point Tbof urea, the heater 50 is actuated to thereby increase the temperatureof the supply system. Then, when the temperature of the supply system ofthe urea aqueous solution reaches the melting point Tb, the ureaprecipitated in the supply system melts and is discharged from theinjection hole of the injection nozzle 20. At this time, because atleast a part of the piping 22 and the heater 50 are covered with theheat insulating member 54, heat generated by the heater 50 is trappedinside the heat insulating member 54 to thereby effectively heat thepiping 22. Therefore, heating efficiency of the supply system of theurea aqueous solution is enhanced to thereby suppress energy consumptionrequired for heating. On the other hand, if the nozzle temperature TN islower than the boiling point Ta of water, a phenomenon in which onlymoisture evaporates from the urea aqueous solution and urea isprecipitated does not occur. If the nozzle temperature TN is equal to orhigher than the melting point Tb of urea, the precipitated ureanaturally melts. Therefore, the heater 50 is stopped from a view pointof suppression of unnecessary energy consumption.

Therefore, it is possible to maintain the supply system of the ureaaqueous solution at a temperature at which the urea is not precipitatedto thereby prevent injection/supply failure of the urea aqueous solutioncaused by clogging of the injection hole of the injection nozzle 20.Therefore, a required amount of urea aqueous solution according to theoperating state of the engine can be injected and supplied to obtainnecessary exhaust emission purification performance.

FIG. 13 shows a seventh embodiment of the temperature maintenancedevice.

In the present embodiment, a heater 58 as the heating device is spirallywound about an area from the piping 22 to the injection nozzle 20. Here,around the heater 58, heat insulating members 60 and 62 are disposed soas to prevent heat generated by the heater 58 from radiating toward theoutside. Control of actuation of the heater 58 is conducted similarly tothat conducted in the sixth embodiment.

Operation and effects of this structure are similar to those of thesixth embodiment and therefore, description thereof will be omitted.However, as another effect, heat of the exhaust emission becomes lesslikely to be transmitted to the injection nozzle 20 by covering theheater 58 wound around the injection nozzle 20 with the heat insulatingmember 62.

In the sixth and seventh embodiments of the present invention, thecontrol unit 52 may control the heater 50 or 58 so that the heater 50 or58 heats at least a part of the supply system of the urea aqueoussolution to or over the melting point Tb of urea when injection andsupply of the urea aqueous solution are stopped. In this way, a state inwhich the injection hole of the injection nozzle 20 is apt to becomeclogged can be prevented. More specifically, the supply system of theurea aqueous solution is heated to or over the melting point Tb of ureaimmediately after stopping of the injection-supply of the urea aqueoussolution and accordingly, precipitation of urea is suppressed to therebysuccessfully prevent clogging of the injection nozzle 20 for the ureaaqueous solution.

As the temperature maintenance device according to the invention, notonly each of the embodiments alone but also a combination of any two ormore embodiments can be employed on condition that there is no technicalcontradiction. In this way, it is possible to effectively maintain thetemperature of the supply system of the urea aqueous solution at thetemperature at which the urea is not precipitated to thereby actuallyexert effects of the invention. In the invention, if a liquid reducingagent other than the urea aqueous solution is used, a boiling point Taof a solvent and a melting point Tb of dissolved matter may be setproperly according to a characteristic of the agent.

The exhaust emission purification apparatus according to the inventionis extremely useful in that the supply system of the liquid reducingagent is maintained at the temperature at which the dissolved matter isnot precipitated to thereby rarely make the injection hole of theinjection nozzle to become clogged and obtain necessary exhaust emissionpurification performance.

1. An engine exhaust emission purification apparatus, comprising: areduction catalytic converter disposed in an engine exhaust system toreduce and purify nitrogen oxides by using a liquid reducing agent; aninjection nozzle for supplying by injection the liquid reducing agent toa flow of an exhaust emission upstream from the reduction catalyticconverter; and a temperature maintenance device for maintaining atemperature of at least a part of a liquid reducing agent supply systemincluding the injection nozzle and piping of the injection nozzle at atemperature lower than a boiling point of a solvent of the liquidreducing agent or equal to or higher than a melting point of dissolvedmatter, wherein the temperature maintenance device comprises a heatingdevice for heating at least a part of the liquid reducing agent supplysystem and a heating control device for controlling the heating device.2. The engine exhaust emission purification apparatus according to claim1, wherein the heating device comprises a heater.
 3. The engine exhaustemission purification apparatus according to claim 1, wherein a heatinsulating member is disposed around at least a part of the liquidreducing agent supply system and the heating device.
 4. The engineexhaust emission purification apparatus according to claim 1, whereinthe heating control device heats at least a part of the liquid reducingagent supply system to a temperature equal to or higher than the meltingpoint of the dissolved matter of the liquid reducing agent by using theheating device when the injection-supply of the liquid reducing agent isstopped.